Microstructure & Texture

the phase fraction

If a microstructure is a mixture — say hard particles scattered through a soft matrix — one of the first questions is: how much of each? The phase fraction answers it: the proportion of the material that is a given phase, usually expressed as a volume fraction between 0 and 1 (or a percentage). Half hard phase and half soft is a phase fraction of 0.5 each.

The everyday way to measure it is beautifully indirect and rests on a stereological fact: on a random polished section, the area fraction a phase occupies equals its volume fraction, and (Delesse's principle) both equal the fraction of random test points that land on it. So you overlay a grid of points on the micrograph, count what fraction fall on the phase of interest, and that point fraction estimates the volume fraction directly — no 3D reconstruction needed. For example, of 500 grid points, 90 land on carbide, giving a carbide volume fraction of 90/500 = 0.18, or 18 percent. Phase fractions can also be predicted from a phase diagram by the lever rule.

Phase fraction matters because properties often scale with it: the strength of a two-phase alloy, the amount of hard wear-resistant carbide, the fraction of ductile phase for toughness, all track how much of each phase is present and are tuned by composition and heat treatment. Honest caveat: the area-equals-volume rule requires a truly random, representative section and enough counts — a biased cut or too few points gives a poor estimate — and it gives volume fraction, which must be converted with densities if you want a weight (mass) fraction.

Point-counting a duplex stainless steel with a 400-point grid gives 210 points on austenite and 190 on ferrite, so the austenite volume fraction is 210/400 = 0.53 and the ferrite 0.47 — close to the intended 50:50 balance that gives this steel its combination of strength and toughness.

Fraction of random points landing on a phase estimates its volume fraction directly — Delesse's area-equals-volume principle at work.

Point- or area-counting gives the volume fraction, not the weight fraction; convert with the phases' densities if you need mass. And the estimate is only as good as the section is random and the count is large.

Also called
volume fraction of a phasephase volume fraction相體積分率