macrostructure
Macrostructure is the structure you can see with the naked eye or a simple magnifier, the coarsest level of the hierarchy. Think of the visible grain in a piece of oak, the swirling pattern on a Damascus knife blade, the layers in plywood, or the crack running across a broken casting. No microscope needed: these features are millimeters to centimeters in size.
More precisely, macrostructure covers features roughly a millimeter and larger: the overall grain flow in a forged part, weld beads and heat-affected zones, porosity and shrinkage cavities in a casting, fiber layout in a composite, and large-scale segregation where composition varies across a big ingot. These are examined by eye, by low-power magnifier, or after etching, and sometimes by radiography (X-ray photographs of the whole part), rather than by microscope.
Macrostructure matters because big flaws often decide whether a part survives: a single large casting pore or a badly aligned weld can start the crack that breaks a component, no matter how good the finer structure is. In wood and composites, the visible fiber direction directly controls strength along versus across the grain. Caveat: macro is the top of the same continuous ladder as micro and nano, the line at about a millimeter is a convention, and the same defect (say a pore) can exist at several scales at once.
A visible pore in a cast aluminum part, or a weld bead and its heat-affected zone, can be seen without any microscope, yet either can decide how long the part lasts.
Macrostructure: large features visible to the eye that can make or break a part.
Macrostructure is not the shape of the part. It is the internal arrangement of large features (grain flow, welds, pores) that happen to be big enough to see, shape is geometry, macrostructure is still about arrangement.