Reciprocal Space & Diffraction

Ewald sphere

/ AY-vahlt SFEER /

Predicting which diffraction spots will show up can feel like guesswork. The Ewald sphere turns it into a clean piece of geometry — like laying a transparent globe over a field of dots and reading off exactly which dots the globe's surface touches. It is a drawing trick that tells you, for a given beam and crystal orientation, precisely which reflections will flash on.

Here is the construction. Draw the reciprocal lattice as a grid of dots. Pick the spot where the incoming beam enters and draw a sphere whose radius is set by the wavelength (one over the wavelength), positioned so its surface passes through the lattice's origin. The rule is simple and exact: a diffraction spot appears for every reciprocal lattice dot that happens to lie on the surface of that sphere. Each such dot satisfies the Laue condition automatically, because the geometry was built to encode it.

This matters because it makes a daunting 3D condition visual and predictive: rotate the crystal and you rotate the dots, sweeping different ones onto the sphere, which is exactly why crystallographers spin their samples to collect a full set of reflections. The honest caveat is that the Ewald sphere is a bookkeeping picture in reciprocal space, not a physical ball inside the crystal — and for short-wavelength electrons the sphere is so large it is nearly flat, which is why electron patterns show many spots at once.

In a rotation experiment, a crystal is slowly turned in the beam. As it turns, reciprocal lattice dots sweep across the Ewald sphere's surface one after another, and each time a dot crosses, a spot flares on the detector — letting the machine harvest hundreds of reflections from every angle.

Rotating the crystal sweeps reciprocal lattice dots through the Ewald sphere, triggering spots.

The Ewald sphere's radius shrinks as the wavelength grows. With long-wavelength X-rays only a few dots can ever touch the sphere, while a stationary crystal in a single-wavelength beam may show no spots at all unless it is oriented or rotated just right.

Also called
sphere of reflection