Reciprocal Space & Diffraction

reciprocal lattice

/ rih-SIP-ruh-kuhl LAT-iss /

Picture the rows of trees in an orchard, all spaced evenly apart. Your eye naturally notices the spacings: how far apart the rows are, and which way they run. The reciprocal lattice is a way of writing down exactly those spacings and directions as a tidy grid of its own. It is a second lattice, living not in ordinary space but in 'wave-space', that carries all the information about how regularly the real crystal repeats.

Here is the precise idea. A crystal repeats its pattern after fixed steps in real space. For each direction of repetition, the reciprocal lattice has a matching point, placed at a distance that is large when the real spacing is small, and small when the real spacing is large — that is what 'reciprocal' means. Mathematically you build it from the crystal's repeat vectors so that each reciprocal point corresponds to a set of evenly spaced planes of atoms. The closer those planes sit, the farther out the reciprocal point lands.

This matters because waves — X-rays, neutrons, electrons — do not 'see' single atoms one by one; they respond to the whole repeating pattern at once, and the reciprocal lattice is the natural map of that response. Every bright spot a crystal scatters lands exactly on a reciprocal lattice point. A common confusion: the reciprocal lattice is not a physical object you could touch, and its points are not atoms — they are bookkeeping markers for the crystal's periodicity, measured in units of one-over-length.

Stretch a crystal so its atoms sit farther apart in one direction. In the reciprocal lattice the matching points squeeze closer together in that same direction — and sure enough, the diffraction spots in an experiment move closer too. The two lattices breathe in opposite ways.

Big real-space spacing means small reciprocal spacing, and the other way around.

The reciprocal lattice depends only on how the crystal repeats, not on what sits inside each repeat. The contents of one repeat unit control how bright each spot is, but not where the spots land.

Also called
dual lattice