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The Calcium Branch: Phospholipase C, IP3, DAG and PKC

The Gq route splits one membrane lipid into two messengers at once. Learn how IP3 unleashes a flood of calcium while DAG switches on protein kinase C — two arms of the same signal working together.

One enzyme, two messengers

When a Gq protein switches on, it activates the membrane enzyme phospholipase C (PLC). PLC does something elegant: it cuts a single membrane lipid (called PIP2) into two second messengers in one stroke. One half, inositol trisphosphate (IP3), floats away into the cytoplasm; the other half, diacylglycerol (DAG), stays put in the membrane. The cell now has two messages travelling on two different routes from a single cut.

IP3 opens the calcium floodgates

IP3 travels to the endoplasmic reticulum — the cell's internal calcium store — and opens channels there. Intracellular calcium rushes out into the cytoplasm, and its level can jump more than tenfold in a fraction of a second. Calcium is itself a powerful second messenger: it triggers smooth-muscle contraction, glandular secretion, and hormone release, depending on the tissue.

This is why Gq-linked receptors matter so much in blood vessels, airways and the gut, where contraction is the headline action. A drug that activates a Gq receptor on vascular smooth muscle raises calcium and constricts the vessel; an antagonist at the same receptor lets it relax — a logic you will recognise behind many cardiovascular and respiratory medicines.

DAG and PKC: the second arm

Meanwhile DAG, still in the membrane, recruits and activates protein kinase C (PKC) — and PKC works best when the calcium freed by IP3 is also high. So the two arms cooperate: IP3 supplies the calcium, DAG supplies the membrane anchor, and together they switch PKC fully on. Like PKA before it, PKC then phosphorylates a family of effector proteins to change cell behaviour over a longer timescale.

Agonist -> Gq-linked receptor -> Gq ON
   Gq -> phospholipase C ON
      PIP2 (membrane lipid) cut into TWO messengers:
         |-- IP3  (soluble)  -> opens ER channels
         |                     -> intracellular calcium SPIKES
         |                        -> contraction / secretion
         |-- DAG  (membrane) -> activates protein kinase C
                                + the high calcium
                                -> PKC phosphorylates effectors
The Gq cascade: one cut, two cooperating messenger arms.