Nuclear Physics

the semi-empirical mass formula

/ Bethe: BAY-tuh; Weizsäcker: VITE-zek-er /

Suppose you want to predict the binding energy of any nucleus without solving the impossible many-body quantum problem. The semi-empirical mass formula does it with a handful of physically motivated terms, each capturing one thing a nucleus 'cares about', with numerical coefficients fitted to measured masses. It is half theory, half curve-fit, and it works remarkably well across the whole chart of nuclides.

The formula writes the binding energy as B(Z,A) = a_V A - a_S A^(2/3) - a_C Z(Z-1)/A^(1/3) - a_A (A-2Z)^2/A + delta. The five pieces are: a volume term a_V A (each nucleon is bound by its neighbours, so binding grows with the number of nucleons); a surface term -a_S A^(2/3) (nucleons on the surface have fewer neighbours, a correction proportional to surface area); a Coulomb term -a_C Z(Z-1)/A^(1/3) (mutual electrostatic repulsion of the protons); an asymmetry term -a_A (A-2Z)^2/A (a quantum-mechanical penalty for departing from equal neutron and proton numbers, rooted in the Pauli principle); and a pairing term delta (nuclei prefer even numbers of like nucleons). The first two terms come straight from picturing the nucleus as a liquid drop.

With coefficients on the order of a_V approximately 15.8, a_S approximately 18.3, a_C approximately 0.71, a_A approximately 23.2 MeV, the formula reproduces the binding-energy curve, predicts the most stable charge Z for a given A (the valley of stability), and estimates the energy released in fission. Its honest limitation is that it is a smooth, collective, liquid-drop picture: it completely misses the shell structure that makes magic-number nuclei extra stable. Those bumps require the shell model on top.

For a fixed mass number A, minimizing the formula over Z gives a parabola of masses; the bottom picks out the most stable isobar. This is why, for example, along the A = 127 chain nuclei beta-decay toward iodine-127.

The mass parabola from the SEMF is the map that tells an unstable nucleus which way to decay.

It is called semi-empirical for a reason: the coefficients are fitted, not derived from first principles, and the smooth formula cannot reproduce the discrete extra stability at magic numbers. Do not use it to explain shell closures.

Also called
SEMFBethe-Weizsäcker formulaWeizsäcker formula液滴質量公式