The Laws of Thermodynamics

the Carnot cycle

/ kar-NOH /

The Carnot cycle is an idealized, perfect cycle of operations that squeezes the absolute maximum possible work out of heat flowing between a hot and a cold reservoir. Named after the French engineer Sadi Carnot, who imagined it in 1824, it is the gold standard against which every real engine is measured. No actual engine can beat it, and understanding it tells you exactly why.

The cycle has four reversible steps run in a loop: an isothermal expansion, absorbing heat Q_h from the hot reservoir at temperature T_h; an adiabatic expansion, cooling with no heat flow down to the cold temperature T_c; an isothermal compression, releasing heat Q_c to the cold reservoir at T_c; and an adiabatic compression back to the start. Because every step is reversible, the Carnot engine achieves the highest efficiency any engine can have between those two temperatures: e = 1 - T_c / T_h, with T in kelvin.

The startling lesson of the Carnot cycle is that the maximum efficiency depends only on the two temperatures, not on the working substance or any clever mechanical design. To do better you must raise T_h or lower T_c; nothing else helps. The honest caveat is that a true Carnot cycle is an unreachable ideal — its reversible steps would take infinitely long — so real engines always fall short, but it fixes the ceiling everyone aims for.

A Carnot engine running between a hot reservoir at T_h = 600 K and a cold one at T_c = 300 K has efficiency e = 1 - T_c / T_h = 1 - 300 / 600 = 0.50, or 50 percent. No real engine between those same two temperatures can ever do better.

Carnot efficiency depends only on the hot and cold temperatures in kelvin.

The Carnot efficiency uses absolute (kelvin) temperatures, never Celsius — plugging in Celsius values gives a badly wrong answer, since the formula relies on 0 K meaning truly zero thermal energy.

Also called
Carnot engine卡諾引擎