outer measure
An outer measure is a first, generous estimate of size that is defined on absolutely every subset, with no admission test required. The idea is to cover a set from outside by simple pieces and take the cheapest such cover; because covering is always possible, every set gets a number. The price of this universality is that an outer measure need not be additive — it only never undershoots.
Formally, an outer measure on a set X is a function mu-star from the power set of X to [0, +infinity] satisfying three conditions: mu-star(empty set) = 0; monotonicity, meaning A contained in B implies mu-star(A) is at most mu-star(B); and countable subadditivity, meaning mu-star of a countable union is at most the sum of the mu-star values of the pieces, even when those pieces overlap or are disjoint.
Outer measures are the standard starting point for constructing genuine measures: one builds an outer measure first (it is easy, requiring only covers), then carves out the sets on which it behaves additively. Carathéodory’s criterion selects exactly those well-behaved sets, and on them the outer measure restricts to a bona fide countably additive measure. So an outer measure is the raw material, and the measure is the refined product.
Subadditivity (at most the sum) is genuinely weaker than additivity (exactly the sum on disjoint sets). The whole construction of Lebesgue measure is the story of upgrading from the former to the latter on a large sigma-algebra.