Dislocations & Line Defects

dislocation density

How many dislocations are in a piece of metal? A lot — and how many turns out to be one of the most useful single numbers you can know about it, because it largely sets how strong the metal is. Dislocation density, written rho (the Greek letter rho), measures this. Because dislocations are lines, the natural way to count them is the total LENGTH of dislocation line packed into a unit volume of crystal: metres of line per cubic metre, which tidies up to units of 1 per square metre (m^-2). Equivalently, it is the number of dislocation lines that pierce a unit area of a cut through the crystal.

The range it spans is enormous, and worth committing to memory. A carefully grown, well-annealed crystal is remarkably clean, with rho as low as 10^10 to 10^12 m^-2. Deform that same metal heavily — roll it, hammer it, draw it into wire — and the dislocation density rockets to 10^15 or even 10^16 m^-2, a jump of ten thousand times or more, thanks to multiplication at Frank-Read sources. To feel the scale: 10^15 m^-2 means that if you laid all the dislocation line in one cubic centimetre end to end, it would stretch about a billion kilometres — several times the distance to the Sun, coiled inside a sugar cube.

Density matters because dislocations get in each other's way. The more of them there are, the more their stress fields overlap and the harder it is for any one of them to glide past the others — this is work hardening, and it is captured by the Taylor relation: the extra shear stress needed to keep deforming grows as tau proportional to G b sqrt(rho). That square-root law is why cold-working strengthens a metal (more rho, higher strength) and why annealing softens it (heat lets dislocations climb, react and annihilate, dropping rho back down). Dislocation density is thus the single microstructural dial that ties together deformation, strengthening, and recovery.

Taylor hardening in copper (G = 48 GPa, b = 0.256 nm, constant alpha about 0.3): going from annealed rho = 10^12 m^-2 to cold-worked rho = 10^15 m^-2 raises the flow-stress term tau = alpha G b sqrt(rho) from 0.3 x 48e9 x 0.256e-9 x sqrt(1e12) = 3.7 MPa to 0.3 x 48e9 x 0.256e-9 x sqrt(1e15) = 117 MPa — the square-root law turns a 1000-fold rise in rho into about a 32-fold rise in strength.

rho (line length per volume, m^-2) rises from ~10^12 (annealed) to ~10^15 (cold-worked); strength scales as sqrt(rho).

The unit m^-2 is not a typo: line length (m) per volume (m^3) reduces to m^-2, the same as counting lines per unit area of a section. High rho makes a metal stronger but less ductile; annealing lowers rho by letting dislocations climb, react, and annihilate.

Also called
rholine length per volume差排密度 rho