a monomer
Before you can string beads into a necklace you need a pile of loose beads. A monomer is that loose bead: a small, reactive molecule that will bond to others of its kind to build up a long polymer chain. The name says it plainly — mono means one, mer means part, so a monomer is one part waiting to be joined. Ethylene gas is the monomer that becomes solid polyethylene; you feed in a tank of small molecules and get out a giant chain.
What makes a molecule able to act as a monomer is having a reactive feature that can open up and link. Very often it is a carbon-carbon double bond: ethylene is CH2=CH2, and under the right conditions that double bond opens so each carbon can grab a neighbour, zipping many ethylenes into one chain. Other monomers carry two reactive ends (like an -OH on one end and a -COOH on the other) so they can join hand to hand into a chain. Change the monomer and you change the plastic: propylene gives polypropylene, vinyl chloride gives PVC, styrene gives polystyrene.
The monomer matters because it is the design choice that sets everything downstream — the side groups it carries decide the finished polymer's stiffness, melting point, and chemistry. One honest caution: monomers are the small, mobile, often volatile starting molecules, and leftover unreacted monomer can be a real problem. Residual vinyl chloride monomer, for example, is toxic, so processors work hard to drive the reaction to completion and strip out what is left. Keep monomer (the free starter) separate from mer (the same unit once it is locked in the chain).
Ethylene (CH2=CH2), a gas at room temperature, is the monomer of polyethylene: pressurise it with an initiator and the double bonds open and thousands of ethylenes zip together into one solid chain.
Choose the monomer and you choose the plastic — different small starting molecules give completely different polymers.
A monomer is the free reactive molecule you start with, not the same thing as the mer (that unit once it is locked into the chain). Leftover monomer can be volatile or toxic, so it is stripped out after reaction.