Chemical Equilibria in Analysis

fraction of dissociation

Picture a bag of a hundred snap-together beads dropped into water; some pairs come apart, most stay joined. The fraction of dissociation simply answers: of all the units you put in, what share have actually broken into pieces? It is the percentage (written as a fraction between 0 and 1) of a dissolved substance that has split into its ions.

Formally, it is the amount of a compound that has dissociated divided by the total amount originally dissolved. A strong acid in water has a fraction of dissociation essentially equal to 1 — it comes apart completely. A weak acid has a fraction far below 1, meaning most of its molecules stay whole at any moment, with only a small slice ionised.

This single number ties together a lot of analytical reasoning: it sets how acidic a weak acid solution really is, and it explains why weak electrolytes behave so differently from strong ones. The honest and slightly surprising caveat is dilution: the fraction of dissociation of a weak acid rises as you dilute the solution. Spread the molecules further apart and a larger share of them break up — even though the total number of ions in the beaker goes down.

In 0.1 M acetic acid only about 1.3% of the molecules are dissociated at any moment (a fraction of about 0.013); dilute it tenfold and that fraction climbs to roughly 4%.

Diluting a weak acid raises its fraction of dissociation.

Do not confuse a high fraction of dissociation with a strong acid in the everyday sense. A very dilute weak acid can be largely dissociated yet still produce few hydrogen ions overall, because there is so little of it dissolved to begin with.

Also called
degree of dissociationalpha解离度解離度