Acids, Bases & Ionic Equilibria

conjugate acid–base pair

Think of a glove turned inside out: it is still the same glove, just missing one thing or wearing one extra. In acid–base chemistry, every acid has a partner that is exactly itself minus one proton, and every base has a partner that is itself plus one proton. Those two are a conjugate acid–base pair — the before-and-after of a single proton handover.

Precisely, when an acid HA gives up its proton, what is left, A-, is its conjugate base; when a base B picks up a proton to become BH+, that BH+ is its conjugate acid. The two differ by just one H+. They always come paired in any Brønsted–Lowry reaction, because the proton an acid releases has to be caught by a base, creating two new conjugate species on the product side.

This pairing matters because it predicts strength: the stronger an acid, the weaker its conjugate base, and vice versa. A strong acid like HCl leaves behind a feeble conjugate base (Cl-) that has no urge to grab the proton back. The idea also powers buffers, where an acid and its conjugate base coexist on purpose to steady the pH.

Acetic acid (CH3COOH) and acetate ion (CH3COO-) are a conjugate pair: drop the proton off the acid and you have the base; put it back and you have the acid again.

A conjugate pair differs by exactly one proton — acid on one side, base on the other.

The pairing is quantitative: for any conjugate pair Ka × Kb = Kw. So a very weak acid (tiny Ka) must have a relatively strong conjugate base (larger Kb). Strength always trades off across the pair.

Also called
共轭酸碱对共軛酸鹼對